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The monograph presents an improved scheme of natural and agricultural zoning of the territory of Ukraine. According to the developed criteria, five natural and agricultural zones (Polissya, Forest-Steppe, Steppe, Arid Steppe, Dry Steppe) and two mountainous regions (Carpathian Mountain Region, Crimean Mountain Region), 19 provinces and 33 districts are specified and distinguished, and their ecological and economic characteristics are given. The natural and agricultural zoning of Rivne, Cherkasy and Zaporizhzhia regions was carried out, with the identification of natural and agricultural areas and their respective environmental and economic characteristics. The Scheme (map) of natural and agricultural zoning of Ukraine and its reference book have been developed . The scientific work will be of interest and use to specialists of the land management service, postgraduate students, co-workers and other scientists in the field of land use and protection.